期刊
ORGANIC LETTERS
卷 24, 期 50, 页码 9216-9221出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c03730
关键词
-
资金
- Basic Research Laboratory Program (BRL)
- Basic Science Research Program of the Korean National Research Foundation - Korean Ministry of Science, ICT, and Future Planning [NRF-2020R1A4A1016142, NRF-2022R1A2C1009252]
This study reports an unprecedented approach to synthesizing xanthone scaffold from cyclohexyl(2-hydroxyphenyl)methanone through dehydrogenative cyclization and aromatization cascade. This method offers a novel route with a high atom-economic manner and a wide substrate scope.
In this study, an unprecedented approach to the xanthone scaffold from cyclohexyl(2-hydroxyphenyl)methanone via dehydrogenative cyclization and a successive aromatization cascade is reported. This methodology affords a novel route to the privileged structure with a wide substrate scope (a total of 29 compounds, <= 96% yield) in a highly atom-economic manner.
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