期刊
ORGANIC LETTERS
卷 24, 期 47, 页码 8586-8591出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c02945
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资金
- IoE, University of Delhi, India
- University Grant Commission, New Delhi, India
A catalyst-free synthetic approach to beta-thiazole-fused 5,10,15,20-tetraarylporphyrins via a cascade reaction of nickel(II) or copper(II) 2-amido-3-bromo-5,10,15,20-tetraarylporphyrins and Lawesson's reagent is described in this study. The novel porphyrins showed significant bathochromic shift in electronic absorption and emission spectra compared to their precursors, meso-tetraarylporphyrins, as revealed by preliminary photophysical studies.
A catalyst-free synthetic approach to beta-thiazole-fused 5,10,15,20-tetraarylporphyrins via a cascade reaction of nickel(II) or copper(II) 2-amido-3-bromo-5,10,15,20-tetraarylporphyrins and Lawesson's reagent is described. During the course of the reaction, 3-bromo-2-thioamido-5,10,15,20-tetraarylporphyrins formed in situ undergo debrominative cyclization in refluxing toluene to provide novel beta-thiazole-fused porphyrin macrocycles in good yields. Furthermore, free-base and zinc(II) beta-thiazole-fused porphyrins have also been constructed in excellent yields by using standard demetalation and zinc metal insertion procedures. The preliminary photophysical studies revealed a significant bathochromic shift in the electronic absorption and emission spectra of new porphyrins as compared to meso-tetraarylporphyrin precursors.
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