期刊
NEW JOURNAL OF CHEMISTRY
卷 47, 期 9, 页码 4346-4354出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj04408k
关键词
-
A novel anthracene-based ligand L1 with imine functionality and tellurium donor moiety was synthesized. The resulting organotellurium ligand L1 was used to prepare palladium complex 1 and ruthenium complex 2. Complexes 1 and 2 were characterized and their molecular structures were confirmed using various spectroscopic techniques. Complex 1 exhibited catalytic activity for O-arylation of phenol, while complex 2 showed good activity for aldehyde to amide conversion.
Anthracene-based ligand L1 comprising an imine functionality and a tellurium (Te) donor moiety has been prepared. This ligand L1 has been characterized using H-1, C-13 and Te-125 NMR spectroscopic techniques. The novel palladium(ii) complex 1 and ruthenium(ii) complex 2 have been synthesized by reacting organotellurium ligand L1 and Na2PdCl4/[Ru p(cymene)Cl-2](2), respectively. The Pd(ii) complex 1 and Ru(ii) complex 2 were characterized with high resolution mass spectrometry (HR-MS) and Te-125 NMR spectra. The molecular structures of complexes 1 and 2 were authenticated with single crystal X-ray diffraction. Both the complexes are thermally stable, robust, and air and moisture insensitive. Palladium complex 1 exhibits nearly square planar geometry. The molecular structure of complex 2 has a pseudo-octahedral half sandwich piano-stool geometry around ruthenium. The catalytic activity of complex 1 has been explored for O-arylation of phenol, whereas the catalytic activity of complex 2 was explored for aldehyde to amide conversion. A variety of structurally different chloroarenes have been coupled with phenol employing 1 as a catalyst. A wide range of aldehydes containing different functional groups (viz. H, -Me, -NO2, F, OMe, Cl and Br at the para position) were readily converted into their corresponding amide by employing Ru(ii) complex 2 as a catalyst in a reaction time of 12 hours.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据