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Multidisciplinary Sciences
Shuvo Jit Datta et al.
Summary: This study reports a highly efficient method for separating hydrogen sulfide and carbon dioxide from natural gas using mixed-matrix metal-organic framework membranes. The membranes, designed and constructed with specific structures, showed exceptional separation performance under practical working conditions. This approach has the potential to translate other key adsorbents into processable matrix.
Article
Biochemical Research Methods
Taimin Yang et al.
Summary: This protocol explains the complete workflow for determining the structure of metal-organic frameworks using three-dimensional electron diffraction, including sample preparation, data acquisition and processing, and structure determination.
Editorial Material
Chemistry, Physical
Satoshi Horike et al.
Summary: Metal-organic frameworks, composed of metal ions and organic molecules, have developed into an innovative chemistry that offers solutions to the challenges in environment, resources, energy, and health faced by humanity in the past 20 years.
Review
Chemistry, Multidisciplinary
Youdong Cheng et al.
Summary: Membrane-based separations have attracted considerable attention due to their energy efficiency, low cost, environmental friendliness, and continuous operation. Metal-organic frameworks (MOFs), as a type of highly porous crystalline materials, have shown great potential as membrane materials. This review provides a comprehensive discussion on the classification, historical development, design strategies, latest advances, and future challenges and opportunities of MOF-based membranes, aiming to guide the design and fabrication of high-performance membranes in the future.
CHEMICAL SOCIETY REVIEWS
(2022)
Review
Chemistry, Multidisciplinary
Weibin Liang et al.
Summary: Enzymes play a crucial role in chemical synthesis and biotechnology, but their activity can be easily affected by external stressors. Metal-organic frameworks (MOFs) offer protection to enzymes through encapsulation or infiltration, allowing them to maintain activity under challenging conditions.
Article
Multidisciplinary Sciences
Jian-Bin Lin et al.
Summary: Zinc-based CALF-20 demonstrates high efficiency and cost-effectiveness in CO2 capture, with the ability to resist water interference, low regeneration cost, and strong durability.
Article
Multidisciplinary Sciences
Nikita Hanikel et al.
Summary: By conducting single-crystal x-ray diffraction experiments and density functional theory calculations, we deciphered the water-filling mechanism in the state-of-the-art water-harvesting metal-organic framework MOF-303. The evolution of water structures led us to modify the pores and precisely modulate the binding strength of water molecules, resulting in higher water productivity and tunability of regeneration temperature and enthalpy without compromising capacity and stability.
Article
Chemistry, Multidisciplinary
Jack D. Evans et al.
Summary: New advanced adsorbents play a crucial role in the development of energy and environmental applications. Machine learning and data mining techniques are powerful tools for identifying suitable adsorbents for specific applications. The proposal of a new standard adsorption information file (AIF) aims to address the inadequacy of current scientific reporting of adsorption isotherms and pave the way for an open adsorption data format.
Article
Chemistry, Physical
Thomas D. Bennett et al.
Summary: Porous materials are usually ordered crystalline solids, but topological disorder may also be useful in creating alternative properties. This research explores the evolution from ordered states to glassy and liquid states, different types of porous liquids, and potential applications of these disordered systems.
Review
Chemistry, Multidisciplinary
Veronique Van Speybroeck et al.
Summary: Metal-organic frameworks (MOFs) are hybrid materials that exhibit anomalous responses to certain triggers, such as negative linear compressibility and negative thermal expansion. By controlling spatial heterogeneities and operating conditions, the dynamic response of MOFs can be adjusted. Studying the spatiotemporal evolution of MOFs under working conditions is significant for materials science.
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Jack D. Evans et al.
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Benjamin J. Bucior et al.
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CHEMICAL SOCIETY REVIEWS
(2017)
Review
Multidisciplinary Sciences
OM Yaghi et al.