4.8 Article

Synergistically boosting the anchoring effect and catalytic activity of MXenes as bifunctional electrocatalysts for sodium-sulfur batteries by single-atom catalyst engineering

期刊

NANOSCALE
卷 15, 期 6, 页码 2747-2755

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nr05930d

关键词

-

向作者/读者索取更多资源

MXene based sulfur hosts have a strong affinity towards soluble sodium polysulfides (NaPSs) in room temperature sodium-sulfur (RT Na-S) batteries. A series of single non-noble transition metal (TM = Fe, Co, Ni, and Cu) atoms anchored on Ti2CS2 (TM@Ti2CS2) were proposed as bifunctional sulfur hosts for Na-S batteries, showing enhanced chemical interaction and improved electrocatalytic performance. The results suggest that constructing single atom catalysts is an effective strategy to further improve the electrochemical performance of MXene based sulfur hosts for Na-S batteries.
MXene based sulfur hosts have attracted enormous attention in room temperature sodium-sulfur (RT Na-S) batteries due to their strong affinity towards soluble sodium polysulfides (NaPSs). However, their electrocatalytic performance needs further improvement. Here, a series of single non-noble transition metal (TM = Fe, Co, Ni, and Cu) atoms anchored on Ti2CS2 (TM@Ti2CS2) were proposed as bifunctional sulfur hosts for Na-S batteries. The results testify that the introduction of TMs dramatically enhanced the chemical interaction between sulfur-containing species and Ti2CS2, which is attributed to the co-formation of TM-S and Na-S covalent bonds. Importantly, compared with pristine Ti2CS2, the sulfur reduction reaction (SRR) is thermodynamically more favorable on TM@Ti2CS2. In addition, the incorporation of Fe, Co, and Ni atoms is also conducive to promoting the dissociation of Na2S. The density of states (DOS) results suggest that TM@Ti2CS2 maintains metallic conductivity during the whole charge and discharge process. Overall, constructing single atom catalysts is an effective strategy to further improve the electrochemical performance of MXene based sulfur hosts for Na-S batteries.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据