Tuning the electron transport behavior at Li/LATP interface for enhanced cyclability of solid-state Li batteries

Article Multidisciplinary Sciences

Elastomeric electrolytes for high-energy solid-state lithium batteries

Michael J. Lee et al.

Summary: Elastomeric solid-state electrolytes with mechanical robustness, high ionic conductivity, low interfacial resistance and high lithium-ion transference number enable stable operation of high-energy, solid-state lithium batteries.

NATURE (2022)

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Article Chemistry, Physical

Solvent-Free Approach for Interweaving Freestanding and Ultrathin Inorganic Solid Electrolyte Membranes

Changhong Wang et al.

Summary: This study successfully fabricated representative SE membranes with thin thickness and high room-temperature ionic conductivity using PTFE fibrilization technology. The all-solid-state pouch cells prepared with this technology exhibited high capacity and cycling stability.

ACS ENERGY LETTERS (2022)

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Review Chemistry, Physical

Garnet Solid Electrolyte for Advanced All-Solid-State Li Batteries

Laiqiang Xu et al.

Summary: This article discusses the importance of all-solid-state lithium batteries in the field of energy storage, explores the challenges faced by garnet-type solid electrolytes, and proposes prospective developments and alternative approaches to solving the issues of solid-state electrolytes.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase

Jian Tan et al.

Summary: Rechargeable lithium batteries have transformed energy storage technology, but their further commercialization is hindered by short lifetime and safety issues, mainly due to the unstable solid-electrolyte interphase (SEI) and uncontrolled lithium dendrite growth. Research on SEI worldwide has focused on its debated structure and composition, particularly the role of the main component LiF. This review covers the development history of the SEI model, fundamental understanding of SEI, categorization of anode materials generating LiF in SEI, characterization techniques of SEI layers, transport mechanism of Li+ ions within SEI, physical properties of LiF, and analysis of LiF sources, offering insights for future research directions to promote large-scale applications of lithium metal batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Multidisciplinary Sciences

A highly stable and flexible zeolite electrolyte solid-state Li-air battery

Xiwen Chi et al.

Summary: Solid-state lithium-air batteries with integrated ultrathin, high-ion-conductive zeolite X membrane as the sole solid electrolyte exhibit excellent electrochemical performance, flexibility, and stability. These batteries have a high capacity and cycle life, outperforming batteries based on other materials under the same conditions, and show potential for practical applicability in various energy-storage systems.

NATURE (2021)

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Article Multidisciplinary Sciences

A dynamic stability design strategy for lithium metal solid state batteries

Luhan Ye et al.

Summary: A multi-layered electrolyte design can inhibit the growth of lithium dendrites in solid-state lithium metal batteries, improving their performance. However, practical challenges remain in realizing a lithium metal anode for batteries.

NATURE (2021)

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Article Chemistry, Physical

Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways

Ying Wang et al.

Summary: The proposed stable solid-state polymer composite electrolyte shows promise for addressing the key challenge of electrolyte compatibility with high-energy-density electrodes in the next generation of lithium-based batteries. This electrolyte possesses outstanding Li+ conductivity and electrochemical stability, potentially enabling safe and high-energy-density energy storage and conversion applications.

NATURE MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Superior All-Solid-State Batteries Enabled by a Gas-Phase-Synthesized Sulfide Electrolyte with Ultrahigh Moisture Stability and Ionic Conductivity

Pushun Lu et al.

Summary: Sulfide solid electrolytes (SEs) are considered promising for all-solid-state batteries (ASSBs) due to their superior ionic conductivity and ductility. A one-step gas-phase synthesis method for sulfide SEs with oxide raw materials in ambient air has been developed, achieving high ionic conductivity. ASSBs with Li3.875Sn0.875As0.125S4 show superior performance, breaking records for reversible capacity and cycle life.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

Electromechanical Failure of NASICON-Type Solid-State Electrolyte-Based All-Solid-State Li-Ion Batteries

Linchun He et al.

Summary: In this study, a bulk all-solid-state Li-ion battery (ASSLiB) was prepared with MnO2-CNT nanocomposite as the anode, LiNi0.5Mn1.5O4 as the cathode, and Li1.5Al0.5Ge1.5(PO4)3 (LAGP) as the solid-state electrolyte. Electrochemical evaluation and first-principles calculations revealed the decomposition of LAGP into various products, resulting in excessive internal stress and crack formation in the solid-state electrolyte.

CHEMISTRY OF MATERIALS (2021)

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Article Multidisciplinary Sciences

Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes

Darren H. S. Tan et al.

Summary: The research successfully achieved stable operation of silicon anodes by using the interface passivating properties of sulfide solid electrolytes. Analysis showed that this approach eliminates continuous interfacial growth and irreversible lithium losses. The promising performance of microsilicon full cells can be attributed to the ideal interface properties between microsilicon and sulfide electrolytes and the unique chemomechanical behavior of the lithium-silicon alloy.

SCIENCE (2021)

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Article Chemistry, Physical

Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive Interlayer

Ruo Zhao et al.

Summary: A metal-organic framework (MOF)-incorporated polymeric layer (ZCPL) was prepared to address the challenges of poor electro-chemical stability and insufficient contact against Li metal in NASICON-type electrolytes for solid-state batteries. ZCPL effectively prevented redox reactions and cracks, while providing fast Li+ transport pathways and ensuring uniform Li+ flow through the interface, leading to long-term cycling stability for both Li symmerical cell and Li/LiFePO4 full cell.

ACS ENERGY LETTERS (2021)

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Article Chemistry, Multidisciplinary

An artificial hybrid interphase for an ultrahigh-rate and practical lithium metal anode

Anjun Hu et al.

Summary: An artificial hybrid SEI layer composed of lithium-antimony alloy and lithium fluoride was constructed to reduce electron tunneling between the Li anode and SEI, resulting in uniform Li deposition and stable Li plating/stripping behaviors at an ultrahigh rate. This work uncovers the internal mechanism of Li+ transport within the SEI component, providing a pathway to stabilize the Li anode under practical high-rate conditions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Electrochemistry

Electrolyte/Electrode Interfaces in All-Solid-State Lithium Batteries: A Review

Yuepeng Pang et al.

Summary: All-solid-state lithium batteries have great potential for higher energy density and safety, but the poor electrode compatibility of solid electrolytes may cause electrolyte/electrode interface degradation, leading to battery failure. Mechanistic analyses and strategies for enhancing electrolyte/electrode interfaces are crucial for the future development of these batteries.

ELECTROCHEMICAL ENERGY REVIEWS (2021)

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Article Chemistry, Physical

Chemomechanical Failure Mechanism Study in NASICON-Type Li1.3Al0.3Ti1.7(PO4)3 Solid-State Lithium Batteries

Jianping Zhu et al.

CHEMISTRY OF MATERIALS (2020)

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Article Energy & Fuels

High-energy long-cycling all-solid-state lithium metal batteries enabled by silver-carbon composite anodes

Yong-Gun Lee et al.

NATURE ENERGY (2020)

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Review Electrochemistry

From Liquid- to Solid-State Batteries: Ion Transfer Kinetics of Heteroionic Interfaces

Manuel Weiss et al.

ELECTROCHEMICAL ENERGY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries

Hanyu Huo et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Electrochemistry

Stable cycling of all-solid-state lithium battery with surface amorphized Li1.5Al0.5Ge1.5(PO4)3 electrolyte and lithium anode

Zhihua Zhang et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Physical

Interphase Morphology between a Solid-State Electrolyte and Lithium Controls Cell Failure

John A. Lewis et al.

ACS ENERGY LETTERS (2019)

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Article Chemistry, Physical

Constructing Multifunctional Interphase between Li1.4Al0.4Ti1.6(PO4)3 and Li Metal by Magnetron Sputtering for Highly Stable Solid-State Lithium Metal Batteries

Xiaoge Hao et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Visualizing Chemomechanical Degradation of a Solid-State Battery Electrolyte

Jared Tippens et al.

ACS ENERGY LETTERS (2019)

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Article Electrochemistry

How Metallic Protection Layers Extend the Lifetime of NASICON-Based Solid-State Lithium Batteries

Francisco Javier Quintero Cortes et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating

Qian Cheng et al.

JOULE (2019)

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Review Chemistry, Multidisciplinary

Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries

Zhonghui Gao et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

Germanium Thin Film Protected Lithium Aluminum Germanium Phosphate for Solid-State Li Batteries

Yijie Liu et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Nanoscience & Nanotechnology

Stabilizing the Interface of NASICON Solid Electrolyte against Li Metal with Atomic Layer Deposition

Yulong Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Multidisciplinary Sciences

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery

Xiulin Fan et al.

SCIENCE ADVANCES (2018)

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Article Electrochemistry

Lithium Metal Penetration Induced by Electrodeposition through Solid Electrolytes: Example in Single-Crystal Li6La3ZrTaO12 Garnet

Tushar Swamy et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

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Article Chemistry, Physical

An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life

Zhihua Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Chemistry, Physical

Regulating Li deposition at artificial solid electrolyte interphases

Lei Fan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Review Nanoscience & Nanotechnology

Lithium battery chemistries enabled by solid-state electrolytes

Arumugam Manthiram et al.

NATURE REVIEWS MATERIALS (2017)

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Article Multidisciplinary Sciences

Toward garnet electrolyte-based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

Kun (Kelvin) Fu et al.

SCIENCE ADVANCES (2017)

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Article Chemistry, Multidisciplinary

Columnar Lithium Metal Anodes

Xue-Qiang Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Article Chemistry, Physical

Mechanical and Thermal Failure Induced by Contact between a Li1.5Al0.5Ge1.5(PO4)3 Solid Electrolyte and Li Metal in an All Solid-State Li Cell

Habin Chung et al.

CHEMISTRY OF MATERIALS (2017)

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Article Electrochemistry

Interfacial Study on Solid Electrolyte Interphase at Li Metal Anode: Implication for Li Dendrite Growth

Z. Liu et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

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Article Energy & Fuels

Design principles for electrolytes and interfaces for stable lithium-metal batteries

Mukul D. Tikekar et al.

NATURE ENERGY (2016)

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Article Nanoscience & Nanotechnology

First-Principles Analysis of Defect Thermodynamics and Ion Transport in Inorganic SEI Compounds: LiF and NaF

Handan Yildirim et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Article Nanoscience & Nanotechnology

Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations

Yizhou Zhu et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Article Chemistry, Multidisciplinary

Enhancement of the Li Conductivity in LiF by Introducing Glass/Crystal Interfaces

Chilin Li et al.

ADVANCED FUNCTIONAL MATERIALS (2012)

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Article Multidisciplinary Sciences

Increasing the conductivity of crystalline polymer electrolytes

AM Christie et al.

NATURE (2005)

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Tuning the electron transport behavior at Li/LATP interface for enhanced cyclability of solid-state Li batteries

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