Surface Coordination of Pd/ZnIn2S4 toward Enhanced Photocatalytic Activity for Pyridine Denitrification

New surface coordination photocatalytic systems that are inspired by natural photosynthesis have significant potential to boost fuel denitrification. Despite this, the direct synthesis of efficient surface coordination photocatalysts remains a major challenge. Herein, it is verified that a coordination photocatalyst can be constructed by coupling Pd and CTAB-modified ZnIn2S4 semiconductors. The optimized Pd/ZnIn2S4 showed a superior degradation rate of 81% for fuel denitrification within 240 min, which was 2.25 times higher than that of ZnIn2S4. From the in situ FTIR and XPS spectra of 1% Pd/ZnIn2S4 before and after pyridine adsorption, we find that pyridine can be selectively adsorbed and form Zn center dot center dot center dot C-N or In center dot center dot center dot C-N on the surface of Pd/ZnIn2S4. Meanwhile, the superior electrical conductivity of Pd can be combined with ZnIn2S4 to promote photocatalytic denitrification. This work also explains the surface/interface coordination effect of metal/nanosheets at the molecular level, playing an important role in photocatalytic fuel denitrification.

Automated summary

By coupling Pd and CTAB-modified ZnIn2S4 semiconductors, a coordination photocatalyst, Pd/ZnIn2S4, is constructed with an enhanced degradation rate of 81% for fuel denitrification within 240 min, which is 2.25 times higher than that of ZnIn2S4. The study also reveals the selective adsorption of pyridine and the formation of Zn…C-N or In…C-N coordination on the surface of Pd/ZnIn2S4. Additionally, this work provides insights into the surface/interface coordination effect of metal/nanosheets at the molecular level in photocatalytic fuel denitrification.