期刊
MOLECULES
卷 27, 期 23, 页码 -出版社
MDPI
DOI: 10.3390/molecules27238537
关键词
photocatalysis; aerobic oxidation; MIL-53(Fe); g-C3N4; heterojunction composite
资金
- National Natural Science Foundation of China
- [22272151]
A MIL-53(Fe)/g-C3N4 heterogeneous composite was synthesized and exhibited excellent photocatalytic activity and stability in the oxidation reaction of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF).
A MIL-53(Fe)/g-C3N4 heterogeneous composite was synthesized and applied in photocatalytic oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF). The systematic investigation indicated that the introduction of MIL-53(Fe) into g-C3N4 increased the specific surface area, broadened the visible-light response region, and promoted the separation efficiency of the photo-generated electron-hole pairs. The 10% MIL-53(Fe)/g-C3N4 heterogeneous composite achieved the best photocatalytic oxidation activity with 74.5% of 5-HMF conversion under simulated sunlight, which was much higher than that of pristine g-C3N4 and MIL-53(Fe). The MIL-53(Fe)/g-C3N4 composite displayed good photocatalytic reusability and stability. Based on the characterization results and photocatalytic performance, a Z-scheme photocatalytic mechanism of the MIL-53(Fe)/g-C3N4 composite was suggested, and a possible reaction route was deduced.
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