4.6 Article

Microchamber Extraction and Analytical Pyrolysis to Explore Volatile Organic Compounds from Compression-Cooking Wood Materials Obtained under Different Conditions

期刊

MOLECULES
卷 27, 期 23, 页码 -

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MDPI
DOI: 10.3390/molecules27238260

关键词

volatile organic compounds; emissions; heartwood; Quercus robur; microchamber; pyrolysis

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Volatile organic compounds are a concern for indoor air quality and are emitted from construction materials. Previous studies on binderless panels mainly focused on optimizing panel characteristics, while this research aims to document emissions from binderless panels and analyze the volatile composition of wood processing through different manufacturing processes.
Volatile organic compounds are species of concern for indoor air quality. They are emitted from a wide range of indoor sources and in particular from construction materials. Industrialized wood-based panels made from various types of wood bonded with thermosetting adhesive resins have been shown to emit volatile organic compounds over months or even years mostly due to the petrochemical binders. Some studies have been conducted on binderless panels, but they mainly focused on the pressing parameters to be applied to optimize the panel characteristics. The aim of this research is to document the emissions from binderless panels and to access the volatile composition of wood processing through the molding of materials. For this purpose, binderless boards were manufactured from hardwoods, known to emit less than softwoods with different thermopressing temperatures and times. Emissions were studied by placing the materials in microchambers. Volatile organic compounds were then sampled and analyzed by various chromatographic methods. On the other hand, materials were pyrolyzed and then analyzed by gas chromatography and mass spectrometry. The implemented protocols proved suitable for the determination of more than 40 organic compounds, among which are aldehydes, aromatics, furans and derivatives, and carboxylic acids.

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