Hydro-isomerization of n-dodecane on Pt-La/Beta catalyst for the production of high quality bio-jet fuel: Effect of La addition

A series of Pt-La/B38 catalysts were prepared for low-temperature isomerization of n-dodecane and the effects of La addition on the textural properties, metal dispersion, acid properties, and catalytic performance were investigated. La co-impregnated with Pt on B38 significantly reduced the Pt size and notably enhanced the uniformity in Pt size. A higher ratio of accessible Pt and medium-strength Bronsted acid sites and a shorter distance between two Pt particles of Pt-La10/B38 resulted in the maximum iso-C12 yield (59.2-56.2%) in the range of 200-250 degrees C, due to the reasonable arrangement of active sites caused by La loading.

Automated summary

The effects of La addition on Pt-La/B38 catalysts for low-temperature isomerization of n-dodecane were investigated. La co-impregnation with Pt reduced the Pt size and improved the uniformity. The reasonable arrangement of active sites caused by La loading resulted in higher iso-C12 yield.