期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 331, 期 -, 页码 42-47出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2015.12.004
关键词
Photodimerization; Crystal engineering; Supramolecular chemistry
资金
- Webster University
- Faculty Development Fund
- National Science Foundation [DMR-1408834]
- California State University San Marcos
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1408834] Funding Source: National Science Foundation
A post-application of dry vortex grinding is used to improve a solid-state photodimerization to near quantitative yield that without grinding does not go to completion. Variable temperature X-ray crystal structure data support the vortex grinding to overcome detrimental effects of static disorder that suppresses the yield of the photoreaction in the solid. (C) 2016 Elsevier B.V. All rights reserved.
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