期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 328, 期 -, 页码 240-248出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2016.05.014
关键词
-
资金
- National Science Foundation [CHE-1440118, CHE-1565782]
- Camille and Henry Dreyfus Foundation
- University of Michigan
Visible light-mediated photoredox catalysis enables the chemoselective reduction of activated carbon-heteroatom bonds as a function of reduction potential. The expansion of the scope of C-X bond reductions towards less activated motifs, such as ethers, amines and sulfides, is important to both organic synthesis and macromolecular degradation method development. In the present report, exploration of photoredox catalysis in alcoholic solvents mediated a decrease in the super-stoichiometric use of (Pr2NEt)-Pr-i and HCO2H in the reduction of alpha-keto ethers, amines and sulfides. Additionally, in the absence of fragmentation, C-C bond formation was afforded, suggesting an intermediate ketyl radicals are present in these transformations. (C) 2016 Elsevier B.V. All rights reserved.
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