4.6 Article

Bulk resistance and internal contacts of carbon fiber paper determined via X-ray computed tomography

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MATERIALS CHEMISTRY AND PHYSICS
卷 296, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2022.127137

关键词

Bulk resistance; Internal contact state; Carbon fiber paper; Fuel cell; X-ray computed tomography

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This study utilized X-ray computed tomography to obtain the fiber distribution and intersection of uncompressed CFP, and established an analytical model of bulk resistance based on the electron transfer path. The results showed that the increase in electron paths and the variation of the contact state were the main factors for the decrease in bulk resistance under compression. The turning points in the contact state curve can be used to assess the mechanical properties of CFP and determine the optimal pressure for fuel cell assembly.
Owing to the challenge of irregular morphology, the impact of compressed carbon fiber paper (CFP) on fuel cell performance and durability is intricate. As a carbon-carbon composite, the internal contact state of CFP directly determines its mechanical and physical properties. In this paper, fiber distribution and intersection of uncom-pressed CFP are achieved by X-ray computed tomography. Then we established an analytical model of bulk resistance based on the electron transfer path and provided a function to describe the internal contact state with strain. The results imply that the increasing number of electron paths and the variation of the contact state are the main factors for the decrease in bulk resistance under compression. The turning points in the contact state curve divide the range of pressure into fiber contact, elastic-plastic deformation and fiber fracture region, which can be used to assess the mechanical properties of CFP and determine the optimal pressure for fuel cell assembly.

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