4.7 Article

Enhanced mechanical properties and high electrical conductivity of copper alloy via dual-nanoprecipitation

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MATERIALS CHARACTERIZATION
卷 195, 期 -, 页码 -

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ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2022.112494

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Cu-Co-Si-Ti-Ce alloy; Precipitation; Multiple strengthening; Mechanical properties

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A Cu-Co-Si-Ti-Ce alloy with medium electrical conductivity and excellent mechanical properties was obtained through vacuum melting process. The combination of multiple strengthening techniques resulted in high micro-hardness and strength. Co2Si and Co16Ti6Si7 phases exhibited coherent and semi-coherent interface relationships with the copper matrix, relieving interfacial stress and reducing interface energy. Solid solution strengthening, work-hardening, grain boundary strengthening, and precipitation strengthening contributed significantly to the alloy's strengthening.
Copper alloys are widely used as lead frames, electric contact wires and pantographs due to their high electrical conductivity and excellent mechanical properties. At present work, a medium electrical conductivity and excellent mechanical properties of Cu-Co-Si-Ti-Ce alloy was obtained by the vacuum melting process with the optimum performance of 225 HV, 702.5 MPa and 40.8% IACS aging at 500 degrees C for 60 min via the combinations of multiple strengthening. It can be inferred that the high-volume fraction of Goss, Brass, copper and S texture was one of the main reasons for the increase of micro-hardness by comparing the texture content at different con-ditions. Moreover, it was observed that Co2Si and Co16Ti6Si7 phases exhibited coherent and semi-coherent interface relationships with the copper matrix, respectively, which can relieve the interfacial stress and reduce the interface energy by GPA analysis. Finally, the contributions of solid solution strengthening, work-hardening, grain boundary strengthening and precipitation strengthening were calculated, contributing most to the pre-cipitation strengthening.

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