Flexible and ultrathin waterproof conductive cellular membranes based on conformally gold-coated PVDF nanofibers and their potential as gas diffusion electrode

Nanofiber membranes (NFMs) coated with noble metals are intensively researched for various applica-tions such as wearable electronics, environmental sensors, and point of care diagnostics. To achieve the desired functionality while minimizing costs, a combination of facile coating methods and accurate microstructural designs is required, but remains elusive. Herein, novel conductive and porous mem-branes are designed based on a facile and scalable approach to fabricating conformally coated gold layers on electrospun PVDF fibers (Au-PVDF-NFMs) via electroless plating. The deposition of a conformal and fully interconnected gold layer with an average thickness of circa 38 nm on the surface of nanofibers is confirmed by systematic characterizations. The high-conjunction gold layers endows a high electrical conductivity to the membranes, yielding a low sheet resistance of 1.2 c2/sq. In addition, the membranes show integrated functionalities such as hydrophobicity and gas permeability. Notably, the NFMs also show excellent mechanical durability under both stretching and bending, with negligible conductivity losses after 1000 test cycles. Thanks to these properties, the Au-PVDF-NFMs demonstrates practical suit-ability as gas diffusion electrodes (GDEs) for electrochemical CO2 reduction. The Au-PVDF-NFMs exhibit a substantial Faradaic efficiency towards CO, as high as ti 85 % at-0.7 V vs reversible hydrogen electrode (RHE), and are able to reach current densities of 100 mA cm-2 at-0.95 V versus RHE.(c) 2022 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).

Automated summary

Novel conductive and porous membranes are designed by facile and scalable approach to fabricating conformally coated gold layers on electrospun PVDF fibers. These membranes exhibit high electrical conductivity, low sheet resistance, hydrophobicity, gas permeability, and excellent mechanical durability. They show practical suitability as gas diffusion electrodes for electrochemical CO2 reduction.