4.6 Article

Processing Temperature Impact on TiNb2O7 Thick All Active Material Lithium-Ion Battery Electrodes

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ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/acb403

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Lithium-ion batteries are widely used for energy storage, and research is focused on improving their properties. Increasing electrode thickness can enhance the loading of active material and reduce inactive components, but it may affect mechanical stability. This study investigates the processing of TiNb2O7 into all active material (AAM) electrodes, which can overcome the limitations in thick lithium-ion electrodes. The results provide insights into fabricating AAM electrodes with multicomponent oxide phases and their electrochemical consequences.
Lithium-ion batteries have become a widespread energy storage technology, and research continues towards improving battery properties. One route to increase electrode areal active material loading and decrease relative volume fractions of inactive components is to increase electrode thickness, but increasing thickness can impact mechanical stability for conventional composite electrodes. All active material (AAM) electrodes, including those in this work, can mitigate mechanical and transport limitations for very thick lithium-ion electrodes. Such electrodes are free of polymer binders and conductive additives, and processed by pressing electroactive material powder into a porous pellet followed by mild sintering to improve mechanical properties. This study investigated the processing of a more recent material processed into AAM electrodes, TiNb2O7, which has relatively high volumetric capacity among reported materials processed into AAM electrodes. The anode material was characterized in AAM electrodes where different processing temperatures were used, resulting in different titanium and niobium containing phases being present. This manuscript provides insights and electrochemical consequences for fabricating AAM electrodes with multicomponent oxide phases.

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