Photophysical characterization of a bisacridinium-diphenylporphyrin conjugate

A molecular conjugate made of a free-base diphenyl porphyrin chromophore (DPP) trans-linked to two N-acridinium units has been synthesized and photophysically characterized in acetonitrile. Interestingly, the emission of both fluorophores is quenched in the array at room temperature. Steady-state and time-resolved optical analysis proved that an ultrafast electron transfer from the porphyrin to the acridinium units occurs upon excitation of either the porphyrin or the acridinium moiety. On the other hand, at low temperature (77 K) the emission of the porphyrin is completely recovered, thanks to the inhibition of the electron transfer, and a photoinduced energy transfer from the acridinium to the porphyrin component is observed.

Automated summary

A molecular conjugate synthesized and characterized in acetonitrile consisted of a free-base diphenyl porphyrin chromophore (DPP) trans-linked to two N-acridinium units. The emission of both fluorophores is quenched in the array at room temperature due to ultrafast electron transfer occurring upon excitation of either the porphyrin or the acridinium moiety. At low temperature (77 K), the emission of the porphyrin is completely recovered and a photoinduced energy transfer from the acridinium to the porphyrin component is observed due to the inhibition of electron transfer.