期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 434, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2022.114239
关键词
Nitrogen heterocycles; Cycloaddition; Photo -reaction; Radical reactions; Domino reactions
In this study, a new method for synthesizing pharmacological drugs using a photosensitizer was proposed. The study showed that imidazolidines can be synthesized through a photocycloaddition reaction under specific conditions. A reaction mechanism was proposed based on quenching experiments, quantum yield, and potential measurements.
Imidazolidine is a saturated heterocycle with a cyclic aminal core that can be used to develop new pharmaco-logical drugs. Heteroleptic cyclometalated Ir(III) complex photosensitizers have been shown to enable the un-precedented synthesis of imidazolidines through a formal [3 + 2] photocycloaddition of aromatic imines with N, N,N',N'-tetramethyldiaminomethane. Herein, a reaction mechanism based on quenching experiments, quantum yield, ground-state redox potentials, and excited-state potentials is proposed.
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