期刊
JOURNAL OF MEMBRANE SCIENCE
卷 664, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.memsci.2022.121088
关键词
Polysulfate; Hollow fiber; UF membrane; Non-solvent induced phase separation
资金
- National Natural Science Foundation of China [21878004, 22125801]
- Beijing Municipal Natural Science Foundation
- Beijing Natural Science Foundation Committee
- Beijing Education Committee [KZ201910005001]
To tailor membrane morphology and performance, understanding the phase separation process of a polymer is crucial. In this study, a novel polysulfate (PSE) was used to fabricate a hollow fiber membrane for ultrafiltration. By adjusting the PSE concentration and air gaps during spinning, the dimension and skin morphology of PSE hollow fiber were tuned to enhance ultrafiltration performance. The optimized PSE hollow fiber achieved high pure water flux, BSA rejection, and flux recovery rate, indicating its promising application in ultrafiltration hollow fiber membrane.
To tailor the morphology and performance of membrane precisely, exploring the principle in the phase separation process of a certain polymer is a crucial step. In this work, a novel polysulfate (PSE) was employed to fabricate a hollow fiber membrane via NIPS method for use in ultrafiltration. The PSE concentration in the dope was varied to thoroughly investigate the phase separation process from both thermodynamic and kinetic aspects. The dimension and skin morphology of the PSE hollow fiber was tuned by altering air gaps during spinning to receive a better ultrafiltration ability. The optimized PSE hollow fiber achieved a pure water flux of 83.2 Lm(-2)h(-1) (LMH), a BSA rejection of 97.9%, and a flux recovery rate of 92%, demonstrating that PSE is a novel polymer with a promising application in ultrafiltration hollow fiber membrane.
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