Metal-organic framework-derived carbon-based composites for electromagnetic wave absorption: Dimension design and morphology regulation

Developing highly efficient microwave absorbing materials (MAMs) to ameliorate the electromagnetic (EM) response and facilitate energy absorption is crucial in both the civil and military industries. Metal -organic framework (MOF) derived nanoporous carbon composites have emerged as advanced MAMs ow-ing to their rich porosity, tunable compositions, facile functionalization, and morphology diversity. To-gether with the flourishing development of composition-tuning strategy, the rational dimension design and elaborate control over the architectures have also evolved into an effective approach to regulating their EM properties. Herein, we provide a comprehensive review of the recent advances in using di-mension and morphology modulation to adjust the microwave attenuation capacities for MOF-derived carbon composites. The underlying design rules and unique advantages for the MAMs of various dimen-sions were discussed with the selection of representative work, providing general concepts and insight on how to efficiently tune the morphologies. Accordingly, the fundamental dimension-morphology-function relationship was also elucidated. Finally, the challenges and perspectives of dimension design and mor-phology control over MOF-derived MAMs were also presented. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

In this article, recent advances in using dimension and morphology modulation to adjust the microwave attenuation capacities for MOF-derived carbon composites are comprehensively reviewed. The fundamental design rules and unique advantages for various dimensions of MAMs are discussed, providing general concepts and insight on how to efficiently tune the morphologies. The fundamental dimension-morphology-function relationship is elucidated, and the challenges and perspectives of dimension design and morphology control over MOF-derived MAMs are presented.