4.7 Review

Research progresses on the application of perovskite in adsorption and photocatalytic removal of water pollutants

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JOURNAL OF HAZARDOUS MATERIALS
卷 442, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.jhazmat.2022.130024

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Perovskites; Wastewater; Adsorption; Photocatalysis

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This paper discusses the advantages of multi-functional perovskites in simultaneously applying adsorption and photocatalytic removal of water pollutants, as well as the preparation methods, influencing factors, and strategies for performance improvement. It explores the removal mechanisms and behaviors of water pollutants using perovskites, providing insights for designing them as efficient adsorbents and catalysts.
The problem of global water pollution and scarcity of water resources is becoming increasingly serious. Multi-functional perovskites can well drive adsorption and photocatalytic reactions to remove water pollutants. There are many advantages of perovskites, such as abundant oxygen vacancies, easily tunable structural morphology, stable crystal state, highly active metal sites, and a wide photo response range. However, there are few reviews on the simultaneous application of perovskite to adsorption and photocatalytic removal of water pollutants. Thus, this paper discusses the preparation methods of perovskite, the factors affecting the adsorption of water environmental pollutants by perovskite, and the factors affecting perovskite photocatalytic water pollutants. The particle size, specific surface area, oxygen vacancies, electron-hole trapping agents, potentials of the valence band, and conduction band in perovskites are significant influencing factors for adsorption and photocatalysis. Strategies for improving the performance of perovskites in the fields of adsorption and photocatalysis are dis-cussed. The adsorption behaviors and catalytic mechanisms are also investigated, including adsorption kinetics and thermodynamics, electrostatic interaction, ion exchange, chemical bonding, and photocatalytic mechanism. It summarizes the removal of water pollutants by using perovskites. It provides the design of perovskites as high -efficiency adsorbents and catalysts for developing new technologies.

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