Emission behavior and impact assessment of gaseous volatile compounds in two typical rural domestic waste landfills

Landfill sites are sources of gaseous volatile compounds. The dumping area (LDA) and leachate storage pool (LSP) of two typical rural domestic waste landfill sites in north China (NLF) and southwest China (SLF) were investigated. We found that 45, 46, 61 and 68 volatile organic compounds (VOC) were present in the air of NLF-LDA, NLF-LSP, SLF-LDA, and SLF-LSP, respectively. And there were 27, 29, 35 and 37 kinds of odorous com-pounds being detected. Oxygenated compounds (>48.88%), chlorinated compounds (>6.85%), and aromatics (>5.46%), such as organic acid, 1-chlorobutane, and benzene, were the most abundant compounds in both landfills. The SLF-LDA had the highest olfactory effect, with a corresponding total odor activity value of 29,635.39. The ozone-formation potential analysis showed that VOCs emitted from SLF landfills had significantly higher potential for ozone formation than those from NLF landfills, with ozone generation potentials of 166.02, 225.86, 2511.82, and 1615.99 mg/m3 for the NLF-LDA, NLF-LSP, SLF-LDA, and SLF-LSP, respectively. Higher chronic toxicity and cancer risk of VOCs were found in the SLF according to method of Risk Assessment Infor-mation System. Based on the sensitivity analysis by the Monte Carlo method, concentrations of benzene, pro-pylene oxide, propylene, trichloroethylene, and N-nitrosodiethylamine, along with exposure duration, daily exposure time, and annual exposure frequency, significantly impacted the risk levels. We provide a scientific basis, which reflects the need for controlling and reducing gaseous pollutants from landfills, particularly rural residential landfills, which may improve rural sanitation.

Automated summary

This study investigated gaseous volatile compounds and odorous compounds from rural domestic waste landfill sites in north China and southwest China. The results showed that organic acids, chlorinated compounds, and aromatics were the most abundant compounds in both landfills. The landfill in southwest China had higher ozone formation potential and higher chronic toxicity and cancer risk. Concentrations of benzene, propylene oxide, propylene, trichloroethylene, and N-nitrosodiethylamine, as well as exposure duration, daily exposure time, and annual exposure frequency, significantly influenced the risk levels. Controlling and reducing gaseous pollutants from landfills, especially rural residential landfills, could improve rural sanitation.