Nutrient released characteristics of struvite-biochar fertilizer produced from concentrated sludge supernatant by fluidized bed reactor

With the exacerbating water eutrophication globally, it is important to recover nitrogen (N) and phosphorus (P) from sewage for recycle. In this study, coconut shell biochar and ethylene diamine tetraacetic acid (EDTA) were added into the designed fluidized bed reactor (FBR) to create struvite-biochar. N and P released from struvite-biochar and the recovery efficiency of N and P from concentrated sludge supernatant were analyzed. Results showed that the optimal operation condition for hydraulic retention time (HRT), pH, Mg/P molar ration, and addition amount EDTA were 90 min, 9.5, 1.2, and 0.2 g/L, respectively. The recovery efficiency of NH4+-N and PO43--P, and purity struvite for FBR were 34.41%-38.05%, 64.95-68.40%, and 84.15%, respectively. The recovery efficiency of NH4+-N and PO43--P were respectively increased by 7.23% and 5.36% when FBR with addition of 0.33 g/L coconut shell biochar, but purity struvite from struvite-biochar decreased by 45.70%. Contents of As, Cd, Pb, and Cr in struvite and struvite-biochar were all lower than Chinese Standard Limits of Fertilizer. Compared to commercial chemical fertilizer, such as superphosphate and urea, struvite-biochar and struvite have slowly released N and P. The amounts of released P, NO3--N and NH4+-N from struvite-biochar were higher than struvite during the five leaching times. Compared with struvite, the total amounts of released P, NO3--N and NH4+-N from struvite-biochar increased by 4.9%, 3.5% and 8.3%, respectively. Therefore, it is valuable to add biochar into FBR to recovery N and P from concentrated sludge supernatant and make struvite-biochar as a slow-release fertilizer.

Automated summary

In this study, struvite-biochar was successfully created by adding coconut shell biochar and EDTA to a designed fluidized bed reactor (FBR). The release of N and P from struvite-biochar and the recovery efficiency of N and P from concentrated sludge supernatant were analyzed. The results showed that the optimal operation conditions for HRT, pH, Mg/P molar ratio, and EDTA addition amount were identified. The addition of biochar improved the recovery efficiency of N and P, but decreased the purity of the struvite product. Struvite-biochar had lower concentrations of As, Cd, Pb, and Cr compared to Chinese Standard Limits of Fertilizer. The slow release of N and P from struvite-biochar and struvite compared to commercial fertilizers was observed. The study demonstrates the value of adding biochar to FBR for N and P recovery and the production of slow-release fertilizers.