Three segments distribution of gas diffusion layer porosity in a proton exchange membrane fuel cell

Porosity is the main parameter of gas diffusion layer and has a great influence on cell output performance. The electrochemical reaction rate is various in different region within the cell and the porous electrode may deform because of extrusion during assembly. So non-uniform distribution of porosity may be more similar to the real structure and can change cell performance. Thus, a 3D, two-phase agglomerate model is established to explore the optimal three segments distributions of porosity both in anode and cathode sides along three directions at different voltages using the optimization algorithm without constrains, and the reasons for these results at 0.2 V, 0.6 V and 0.8 V are also emphatically analyzed. The results indicate that the average of optimal porosity in three directions decreases with voltage increasing. With voltage increasing, optimal porosity increases from inlet to outlet, and the value increases along width direction. When cell voltage is 0.2 V, the reaction rate is mainly determined by reactant content, but it is influenced by charge transfer near inlet region. At 0.6 V, the rate is related to charge transmission, but it is affected by reactant content near outlet region.

Automated summary

Porosity is a key parameter affecting the performance of gas diffusion layer in fuel cells. Non-uniform distribution of porosity can better simulate real structure and change cell performance. An optimized three-segment distribution of porosity in anode and cathode sides along three directions at different voltages was explored using a 3D, two-phase agglomerate model, and the reasons for these results at 0.2V, 0.6V and 0.8V were analyzed. The results show that as voltage increases, the average optimal porosity decreases and the porosity increases from inlet to outlet and along width direction. The reaction rate is influenced by reactant content and charge transfer at different regions depending on the voltage.