期刊
JOURNAL OF ELASTICITY
卷 -, 期 -, 页码 -出版社
SPRINGER
DOI: 10.1007/s10659-022-09983-4
关键词
Chromonic liquid crystals; Nematic liquid crystals; Curvature elasticity; Quartic free energy
Chromonic liquid crystals are attracting interest for their adaptability to living systems. The classical theory for describing their elastic properties requires small twist constants and large saddle-splay constants, violating some inequalities and leading to paradoxical consequences. To overcome these issues, a novel elastic theory is proposed, extending the classical Oseen-Frank stored energy by adding a quartic twist term. The total energy of droplets is bounded below in the quartic twist theory, resolving the known paradoxes.
Chromonic liquid crystals are lyotropic materials which are attracting growing interest for their adaptability to living systems. To describe their elastic properties, the classical Oseen-Frank theory requires anomalously small twist constants and (comparatively) large saddle-splay constants, so large as to violate one of Ericksen's inequalities, which guarantee that the Oseen-Frank stored-energy density is bounded below. While such a violation does not prevent the existence and stability of equilibrium distortions in problems with fixed geometric confinement, the study of free-boundary problems for droplets has revealed a number of paradoxical consequences. Minimizing sequences driving the total energy to negative infinity have been constructed by employing ever growing needle-shaped tactoids incorporating a diverging twist (Paparini and Virga in Phys. Rev. E 106: 044703, 2022). To overcome these difficulties, we propose here a novel elastic theory that extends for chromonics the classical Oseen-Frank stored energy by adding a quartic twist term. We show that the total energy of droplets is bounded below in the quartic twist theory, so that the known paradoxes are ruled out. The quartic term introduces a phenomenological length a in the theory; this affects the equilibrium of chromonics confined within capillary tubes. Use of published experimental data allows us to estimate a.
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