4.7 Article

Polymer segmental dynamics near the interface of silica particles in the particle/polymer composites

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Summary: Imaging rotational fluorescence correlation microscopy was used to directly observe the segmental dynamics of a polymer near the polymer-substrate interface. The probe-tethered polymer brush provided spatial selectivity to probe only the segmental dynamics near the interface. The perturbation caused by the grafted polymer chains on the segmental dynamics of the polymer film was minimized by reducing the molecular weight of the polymer brush and using a low grafting density. The polymer dynamics near the interface were found to be insensitive to moderate differences in enthalpic interaction between the polymer and the substrate.

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