期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 629, 期 -, 页码 805-812出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2022.09.016
关键词
MnCo2O4 nanowire; ElectrocatalyticNO(3)(-) reduction; Ambient ammonia synthesis; Spinel-type oxide; Density functional theory
In this study, a self-supported spinel-type MnCo2O4 nanowire array was demonstrated to efficiently catalyze the conversion of NO3- to NH3 under ambient conditions, achieving excellent electrocatalytic performance.
Direct electrocatalytic reduction of nitrate (NO3- ) is an efficient route to simultaneously synthesize ammonia (NH3) and remove NO3- pollutants under ambient conditions, however, it is hindered by the lack of efficient and stable catalysts. Herein, a self-supported spinel-type MnCo2O4 nanowire array is demonstrated for exclusively catalyzing the conversion of NO3- to NH3, achieving a high Faradic efficiency of 97.1% and a large NH3 yield of 0.67 mmol h-1 cm(-2). Furthermore, density functional analysis reveals that MnCo2O4 (220) surface has high activity for NO3- reduction with a low energy barrier of 0.46 eV for *NO to *NOH. (C) 2022 Elsevier Inc. All rights reserved.
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