4.7 Article

Nitrogen-Doped Bismuth Nanosheet as an Efficient Electrocatalyst to CO2 Reduction for Production of Formate

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Bi2O3/BiO2 Nanoheterojunction for Highly Efficient Electrocatalytic CO2 Reduction to Formate

Xuezhen Feng et al.

Summary: Heterostructure engineering plays a vital role in regulating the material interface, thus boosting the electron transportation pathway in advanced catalysis. This study synthesized a novel Bi2O3/BiO2 heterojunction catalyst and observed rich structural dynamics. The heterojunction catalyst exhibited high selectivity and performance in the electrocatalytic CO2 reduction reaction.

NANO LETTERS (2022)

Article Engineering, Chemical

Bismuth-Nanosheet-Based Catalysts with a Reconstituted Bi0 Atom for Promoting the Electrocatalytic Reduction of CO2 to Formate

Jian Wu et al.

Summary: The electrocatalytic reduction of CO2 to valuable chemicals and fuels has great potential. In this study, a method for preparing two-dimensional Bi-based catalysts was developed by reconstituting Bi-0 atoms. Raman spectral analysis revealed that the reconstituted Bi-0 atoms were the active centers for electrocatalysis. The prepared catalyst showed excellent electrocatalytic activity and long-term stability.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2022)

Article Chemistry, Physical

A Mn single atom catalyst with Mn-N2O2 sites integrated into carbon nanosheets for efficient electrocatalytic CO2 reduction

Wenfei Dong et al.

Summary: The electrocatalytic reduction of CO2 using electricity produced from renewable resources is an effective strategy for reducing CO2 emissions and promoting sustainable energy development. This study successfully synthesized a low Mn-content single-atom catalyst with efficient electrocatalytic performance for the CO2 reduction reaction.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Physical

Analyzing the effect of nitrogen/sulfur groups' density ratio in porous carbons on the efficiency of CO2 electrochemical reduction

Wanlu Li et al.

Summary: The study synthesized N and S co-doped carbon materials and found that the best performing sample for CO2 electrochemical reduction had the highest dispersion of N and S heteroatoms, and relatively high density of nitrogen-containing groups and thiophenic groups. The Faradaic efficiency for CO reduction showed a linear decrease with an increase in the ratio of nitrogen groups to sulfur, indicating the enhancing effect of high dispersion of N-containing catalytic centers and their activation by sulfur co-doping on CO2 electroreduction. Additionally, the catalytic activity of pyridinic groups was more positively affected by sulfur co-doping compared to quaternary nitrogen species.

APPLIED SURFACE SCIENCE (2021)

Article Chemistry, Multidisciplinary

Engineering Bismuth-Tin Interface in Bimetallic Aerogel with a 3D Porous Structure for Highly Selective Electrocatalytic CO2 Reduction to HCOOH

Zexing Wu et al.

Summary: The study introduced the use of a metallic bismuth-tin aerogel for electrochemical reduction of CO2 with selective formic acid production, demonstrating high FEHCOOH and stability. Experimental and theoretical findings confirmed that the coexistence of bismuth and tin optimized the energy barrier for formic acid generation, enhancing catalytic activity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Materials Science, Multidisciplinary

Advances in electrochemical reduction of carbon dioxide to formate over bismuth-based catalysts

Yu-Hong Wang et al.

Summary: Bismuth-based catalysts offer advantages of non-toxicity, low cost, and high abundance for electrochemical reduction of CO2 to formate. These catalysts exhibit excellent selectivity and stability in aqueous electrolytes, making them commercially viable for this purpose. This review discusses the performance evaluation, reaction mechanisms, and potential advancements in the field.

RARE METALS (2021)

Article Chemistry, Physical

Tuning the Microenvironment in Gas-Diffusion Electrodes Enables High-Rate CO2 Electrolysis to Formate

Zhuo Xing et al.

Summary: Tuning the microenvironment of Bi-based catalyst in a gas-diffusion-electrode (GDE) by adding hydrophobic polytetrafluoroethylene (PTFE) nanoparticles substantially enhances CO2 electrolysis, achieving high formate production rates and CO2 conversion efficiencies.

ACS ENERGY LETTERS (2021)

Article Nanoscience & Nanotechnology

Synthesis of Cu2O Nanostructures with Tunable Crystal Facets for Electrochemical CO2 Reduction to Alcohols

Bingqian Liu et al.

Summary: Electrochemical CO2 reduction using nanosized Cu2O catalysts with different crystal facets showed variations in CO2 reduction performance and alcohol selectivity, with Cu2O-o demonstrating the highest reduction activity and alcohol yield. This work provides a new route for enhancing the alcohol selectivity of nanostructured Cu2O catalysts through crystal facet engineering.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Large-Area Vertically Aligned Bismuthene Nanosheet Arrays from Galvanic Replacement Reaction for Efficient Electrochemical CO2 Conversion

Jia Fan et al.

Summary: In this work, it is demonstrated that the galvanic replacement reaction is an effective method for preparing high-quality bismuthene nanosheet arrays, enabling the growth of small-thickness, large-surface-area bismuthene nanosheets on copper substrates, and achieving efficient CO2 reduction reactions.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Separated growth of Bi-Cu bimetallic electrocatalysts on defective copper foam for highly converting CO2 to formate with alkaline anion-exchange membrane beyond KHCO3 electrolyte

Luwei Peng et al.

Summary: By forming a Bi-Cu interface on defective copper foam, a bimetallic electrode was designed to efficiently convert CO2 to formate, demonstrating superior performance and durability during electrolysis, inspiring a set of concepts related to CO2 reduction reaction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Integrated Capture and Electroreduction of Flue Gas CO2 to Formate Using Amine Functionalized SnOx Nanoparticles

Yingying Cheng et al.

Summary: By grafting alkanol-amines on a tin oxide surface, the study successfully integrated CO2 capture and electrochemical conversion of flue gas, achieving high Faradaic efficiency for formate production. Surface amino groups not only enrich CO2 and inhibit O2 reduction, but also accelerate CO2 reduction by promoting the formation of key intermediates.

ACS ENERGY LETTERS (2021)

Article Chemistry, Physical

A hierarchical CoP@NiCo-LDH nanoarray as an efficient and flexible catalyst electrode for the alkaline oxygen evolution reaction

Wenli Tian et al.

Summary: This study reports the electrochemical deposition of ultrathin NiCo-layered double hydroxide nanosheets on metallic CoP nanowire arrays directly grown on carbon cloth, demonstrating efficient catalyzing of the alkaline oxygen evolution reaction. The new material shows lower overpotential compared to its counterparts, indicating higher catalytic efficiency and good durability.

SUSTAINABLE ENERGY & FUELS (2021)

Article Chemistry, Multidisciplinary

Molten-Salt-Assisted Synthesis of Bismuth Nanosheets for Long-term Continuous Electrocatalytic Conversion of CO2to Formate

Luocai Yi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

Atom vacancies induced electron-rich surface of ultrathin Bi nanosheet for efficient electrochemical CO2 reduction

Meiming Zhao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Article Chemistry, Multidisciplinary

Surface Nitrogen-Injection Engineering for High Formation Rate of CO2 Reduction to Formate

Han Cheng et al.

NANO LETTERS (2020)

Article Chemistry, Multidisciplinary

Discovery of main group single Sb-N4 active sites for CO2 electroreduction to formate with high efficiency

Zhuoli Jiang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C-C Coupling from CO2 Reduction Reaction

Hyejin Jung et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine

Etienne Boutin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Nanoscience & Nanotechnology

Restructuring of Cu2O to Cu2O@Cu-Metal-Organic Frameworks for Selective Electrochemical Reduction of CO2

Xinyi Tan et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Physical

The importance of morphology on the activity of lead cathodes for the reduction of carbon dioxide to formate

James E. Pander et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Physical

Selective electrochemical reduction of carbon dioxide to formic acid using indium-zinc bimetallic nanocrystals

Ik Seon Kwon et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Physical

Electrochemical reduction of CO2 on defect-rich Bi derived from Bi2S3 with enhanced formate selectivity

Ying Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Multidisciplinary

Reduced SnO2 Porous Nanowires with a High Density of Grain Boundaries as Catalysts for Efficient Electrochemical CO2-into-HCOOH Conversion

Bijandra Kumar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Ultrathin Co3O4 Layers Realizing Optimized CO2 Electroreduction to Formate

Shan Gao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Metal-Doped Nitrogenated Carbon as an Efficient Catalyst for Direct CO2 Electroreduction to CO and Hydrocarbons

Ana Sofia Varela et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate

Narayanaru Sreekanth et al.

CHEMICAL COMMUNICATIONS (2015)

Article Multidisciplinary Sciences

Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction

Bijandra Kumar et al.

NATURE COMMUNICATIONS (2013)

Article Chemistry, Physical

Origin of the overpotential for oxygen reduction at a fuel-cell cathode

JK Norskov et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2004)