☆ 4.7 Review

High-Throughput Strategies for the Design, Discovery, and Analysis of Bismuth-Based Photocatalysts

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2023)

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Summary: This study successfully prepared an S-scheme heterojunction photocatalyst with a nanosheets-on-nanosheets structure and achieved efficient photocatalytic hydrogen production under visible light. The optimal proportion of the heterojunction photocatalyst exhibited remarkably high hydrogen production efficiency, attributed to the increased reactive active sites and the formation of the S-scheme heterojunction, promoting the transfer of photogenerated electron-hole pairs.

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Tuning oxygen vacancy in Bi2WO6 by heteroatom doping for enhanced photooxidation-reduction properties

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Summary: Heteroatom doping was used to synthesize S,F-codoped Bi2WO6 photocatalysts with suitable oxygen vacancies, which exhibited enhanced photooxidation-reduction performance for Cr(VI) reduction and MO degradation under visible light. The control of surface oxygen vacancies through adjusting the S/F ratio during the doping process modulated the band structure and photogenerated charge behavior of Bi2WO6. The optimized S0.10F-Bi2WO6 showed excellent photooxidation-reduction performance, with 1.6 and 2.6 times higher efficiencies for Cr(VI) reduction and MO degradation compared to pristine Bi2WO6 without oxygen vacancy under visible light, respectively.

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Construction of dual Z-scheme Bi2WO6/g-C3N4/black phosphorus quantum dots composites for effective bisphenol A degradation

Fuyou Du et al.

Summary: A novel dual Z-scheme Bi2WO6/g-C3N4/black phosphorus quantum dots (Bi2WO6/g-C3N4/BPQDs) composite was fabricated and used for the photocatalytic degradation of bisphenol A (BPA) under visible-light irradiation. By optimizing the mass ratio of g-C3N4 and BPQDs in the Bi2WO6/g-C3N4/BPQDs composite, the visible-light harvesting capacity was enhanced and the charge separation efficiency and transfer rate of excited-state electrons and holes were increased, resulting in significantly higher photocatalytic activity for BPA degradation. Radical trapping experiments revealed the crucial roles of photogenerated holes (h+) and superoxide radicals (•O2-) in the photocatalytic degradation of BPA. The possible degradation pathway and photocatalytic mechanism were proposed by analyzing the BPA intermediates. Furthermore, the study demonstrated the stability and promising potential of Bi2WO6/g-C3N4/BPQDs as effective photocatalysts for removing environmental contaminants from real water samples.

JOURNAL OF ENVIRONMENTAL SCIENCES (2023)

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Article Chemistry, Physical

Photocatalytic water splitting on BiVO4: Balanced charge-carrier consumption and selective redox reaction

Xiangjiu Guan et al.

Summary: The interrelationship between photocatalytic activity and surficial reaction sites on BiVO4 photocatalyst was investigated by controlling the ratio of reductive and oxidative sites. The results showed that BiVO4 with a medium ratio of reductive/oxidative sites exhibited superior photocatalytic water oxidation and further modification with appropriate cocatalysts achieved efficient overall water splitting. The excellent photocatalytic performance was attributed to balanced charge-carrier consumption.

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Recent advances in bismuth-based photocatalysts: Environment and energy applications

Sijia Song et al.

Summary: Photocatalysis is an effective solution to address environmental pollution and energy shortage, with Bi-based photocatalysts being a popular research topic. This review provides a summary of Bi-based photocatalysts, including their applications in organic pollutant removal, hydrogen production, and oxygen production. The review also highlights the preparation strategies to enhance photocatalytic performance and discusses the possible photocatalytic mechanism, offering new insights for the fabrication of efficient Bi-based photocatalysts. Finally, the current challenges and future development directions of Bi-based photocatalysts are summarized.

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The construction of a highly efficient p-n heterojunction Bi2O3/BiVO4 for hydrogen evolution through solar water splitting

Falak Shafiq et al.

Summary: A novel p-n heterojunction Bi2O3/BiVO4 sample was prepared for efficient hydrogen energy production. The as-prepared 3% Bi2O3/BiVO4 showed an outstanding hydrogen evolution rate of 171.13 mmol h-1 g-1, which was 16 times higher than that of the pure sample, attributed to its unique crystal structure, morphology, high surface area, and extended region of visible light.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

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Microwave hydrothermal synthesis of a Bi2SiO5/Bi12SiO20 heterojunction with oxygen vacancies and multiple charge transfer for enhanced photocatalytic activity

Qi Zhang et al.

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Alkali-mediated dissolution-recrystallization strategy for in situ construction of a BiVO4/Bi25VO40 heterojunction with promoted interfacial charge transfer: Formation mechanism and photocatalytic tetracycline degradation studies

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In-situ construction of β-Bi2O3/Ag2O photocatalyst from deactivated AgBiO3 for tetracycline degradation under visible light

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Recent advances in degradation of organic pollutant in aqueous solutions using bismuth based photocatalysts: A review

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EDTA-2Na assisted facile synthesis of monoclinic bismuth vanadate (m-BiVO4) and m-BiVO4/rGO as a highly efficient visible-light-driven photocatalyst

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Biomass-derived carbon quantum dots modified Bi2MoO6/Bi2S3 heterojunction for efficient photocatalytic removal of organic pollutants and Cr (VI)

Pei Peng et al.

Summary: A Bi2MoO6/carbon quantum dots/Bi2S3 composite material was successfully fabricated and used as a high-efficient photocatalyst for degradation of organic pollutants and reduction of Cr (VI). The carbon quantum dots derived from waste sludge biomass enhanced the photocatalysis activity of the heterojunction. The degradation efficiency of tetracycline hydrochloride reached 92.8% under visible light.

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Morphology-dependent photocatalytic and photoelectrochemical performance of bismuth oxybromide crystals applied to malachite green dye degradation

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Summary: Bismuth ferrite nanostructure, BiFeO3 (BFO), a member of the perovskite family, was synthesized using a chemical route and sintered at 800 degrees Celsius for 6 hours. The crystalline phase, morphology, and particle size of the BFO samples were investigated using XRD, SEM, and TEM, respectively. The prepared material exhibited pseudocapacitive behavior and a low charge transfer resistance.

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Construction of Bi2WO6/ZnIn2S4 with Z-scheme structure for efficient photocatalytic performance

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Summary: Bi2WO6/ZnIn2S4 composites with Z-scheme structure were successfully prepared in this study, exhibiting enhanced photocatalytic performance with the highest efficiency of 97.5% for degrading methyl orange. The composites can degrade various organic pollutants without selectivity and maintain an efficiency of over 90% after multiple reuses, attributed to the rapid transfer of carriers inhibiting the recombination of electrons and holes.

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A review of bismuth-based photocatalysts for antibiotic degradation: Insight into the photocatalytic degradation performance, pathways and relevant mechanisms

Kena Qin et al.

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ENVIRONMENTAL RESEARCH (2021)

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Bi4O5Br2 nanosheets with vertical aligned facets for efficient visible-light-driven photodegradation of BPA

Zhaohui Wu et al.

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Visible-light-responsive graphene-functionalized Bi-bridge Z-scheme black BiOCl/Bi2O3 heterojunction with oxygen vacancy and multiple charge transfer channels for efficient photocatalytic degradation of 2-nitrophenol and industrial wastewater treatment

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A novel synergy of Er3+/Fe3+ co-doped porous Bi5O7I microspheres with enhanced photocatalytic activity under visible-light irradiation

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Monodisperse bismuth nanoparticles decorated graphitic carbon nitride: Enhanced visible-light-response photocatalytic NO removal and reaction pathway

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Preparation of novel p-n heterojunction Bi2O2CO3/BiOBr photocatalysts with enhanced visible light photocatalytic activity

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Bi Cocatalyst/Bi2MoO6 Microspheres Nanohybrid with SPR-Promoted Visible-Light Photocatalysis

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Enhanced visible light photocatalytic performance of a novel heterostructured Bi4O5Br2/Bi24O31Br10/Bi2SiO5 photocatalyst

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Light-Driven Organocatalysis Using Inexpensive, Nontoxic Bi2O3 as the Photocatalyst

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Solvothermal synthesis of novel hierarchical Bi4O5I2 nanoflakes with highly visible light photocatalytic performance for the degradation of 4-tert-butylphe

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In-situ one-step synthesis of novel BiOCl/Bi24O31Cl10 heterojunctions via self-combustion of ionic liquid with enhanced visible-light photocatalytic activities

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Nucleation control and growth mechanism of pure α-Bi2O3 nanowires

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Facile anion-exchange synthesis of BiOI/BiOBr composite with enhanced photoelectrochemical and photocatalytic properties

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CERAMICS INTERNATIONAL (2014)

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Photoactive β-Bi2O3 architectures prepared by a simple solution crystallization method

Yan Lu et al.

CERAMICS INTERNATIONAL (2014)

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A semimetal bismuth element as a direct plasmonic photocatalyst

Fan Dong et al.

CHEMICAL COMMUNICATIONS (2014)

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Article Engineering, Environmental

Hierarchical porous BiOI architectures: Facile microwave nonaqueous synthesis, characterization and application in the removal of Congo red from aqueous solution

Lunhong Ai et al.

CHEMICAL ENGINEERING JOURNAL (2014)

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Article Materials Science, Multidisciplinary

Facile synthesis of β-Bi2O3/Bi2O2CO3 nanocomposite with high visible-light photocatalytic activity

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MATERIALS LETTERS (2014)

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Article Materials Science, Multidisciplinary

Hydrothermal synthesis of Ca3Bi8O15 rods and their visible light photocatalytic properties

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MATERIALS RESEARCH BULLETIN (2014)

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Article Engineering, Electrical & Electronic

The preparation of BiOCl photocatalyst and its performance of photodegradation on dyes

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MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2014)

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Article Chemistry, Multidisciplinary

Hierarchical dielectric orders in layered ferroelectrics Bi2SiO5

Younghun Kim et al.

IUCRJ (2014)

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Article Chemistry, Multidisciplinary

Ferroelectricity Driven by Twisting of Silicate Tetrahedral Chains

Hiroki Taniguchi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

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Article Chemistry, Physical

In situ synthesis of α-β phase heterojunction on Bi2O3 nanowires with exceptional visible-light photocatalytic performance

Jungang Hou et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2013)

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Article Chemistry, Physical

Facile large-scale synthesis of beta-Bi2O3 nanospheres as a highly efficient photocatalyst for the degradation of acetaminophen under visible light irradiation

Xin Xiao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2013)

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Article Chemistry, Multidisciplinary

Efficient Separation of Photogenerated Electron-Hole Pairs by the Combination of a Heterolayered Structure and Internal Polar Field in Pyroelectric BiOIO3 Nanoplates

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CHEMISTRY-A EUROPEAN JOURNAL (2013)

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Article Chemistry, Inorganic & Nuclear

Revisiting the Spectroscopy of the Bi3+ Ion in Oxide Compounds

Philippe Boutinaud

INORGANIC CHEMISTRY (2013)

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Article Physics, Condensed Matter

Structural study of α-Bi2O3 under pressure

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JOURNAL OF PHYSICS-CONDENSED MATTER (2013)

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Synthesis and characterization of Bi12O17Cl2 nanowires obtained by chlorination of α-Bi2O3 nanowires

Li-Chia Tien et al.

MATERIALS LETTERS (2013)

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Article Chemistry, Physical

Facile in situ synthesis of a Bi/BiOCl nanocomposite with high photocatalytic activity

Sunxian Weng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Article Chemistry, Physical

Carbon spheres supported visible-light-driven CuO-BiVO4 heterojunction: Preparation, characterization, and photocatalytic properties

Weirong Zhao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2012)

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Article Chemistry, Physical

Microemulsion synthesis, characterization of bismuth oxyiodine/titanium dioxide hybrid nanoparticles with outstanding photocatalytic performance under visible light irradiation

Zhang Liu et al.

APPLIED SURFACE SCIENCE (2012)

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Article Engineering, Environmental

Design and controllable synthesis of α-/γ-Bi2O3 homojunction with synergetic effect on photocatalytic activity

Yuanyuan Sun et al.

CHEMICAL ENGINEERING JOURNAL (2012)

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Article Engineering, Environmental

Microwave-assisted synthesis of hierarchical Bi7O9I3 microsheets for efficient photocatalytic degradation of bisphenol-A under visible light irradiation

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CHEMICAL ENGINEERING JOURNAL (2012)

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Template-Free Fabrication of Bi2O3 and (BiO)2CO3 Nanotubes and Their Application in Water Treatment

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CHEMISTRY-A EUROPEAN JOURNAL (2012)

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Oxygen-rich bismuth oxyhalides: generalized one-pot synthesis, band structures and visible-light photocatalytic properties

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JOURNAL OF MATERIALS CHEMISTRY (2012)

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Facile Fabrication of Tunable Bi2O3 Self-Assembly and Its Visible Light Photocatalytic Activity

Manickavachagam Muruganandham et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

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Synthesis and Facet-Dependent Photoreactivity of BiOCl Single-Crystalline Nanosheets

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Article Materials Science, Multidisciplinary

Effect of solvents on morphology and photocatalytic activity of BiOBr synthesized by solvothermal method

ZhangSheng Liu et al.

MATERIALS RESEARCH BULLETIN (2012)

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Article Chemistry, Physical

Singular characteristics and unique chemical bond activation mechanisms of photocatalytic reactions on plasmonic nanostructures

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NATURE MATERIALS (2012)

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Novel urea assisted hydrothermal synthesis of hierarchical BiVO4/Bi2O2CO3 nanocomposites with enhanced visible-light photocatalytic activity

Puttaswamy Madhusudan et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2011)

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Article Chemistry, Physical

Photocatalytic study of BiOCl for degradation of organic pollutants under UV irradiation

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JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2010)

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The effects of solvents on the formation of sol-gel-derived Bi12SiO20 thin films

Asja Veber et al.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2010)

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Synergistic effect of crystal and electronic structures on the visible-light-driven photocatalytic performances of Bi2O3 polymorphs

Hefeng Cheng et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2010)

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Bi2O3 Hierarchical Nanostructures: Controllable Synthesis, Growth Mechanism, and their Application in Photocatalysis

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CHEMISTRY-A EUROPEAN JOURNAL (2009)

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Merging photoredox catalysis with organocatalysis: The direct asymmetric alkylation of aldehydes

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SCIENCE (2008)

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Modelling the crystal structures of Aurivillius phases

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SOLID STATE IONICS (2001)

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