期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 48, 期 36, 页码 13479-13488出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.12.300
关键词
Bismuth vanadate(BiVO4); Photoanode; Water oxidation; Hydrogen; Concentrated light
Photoelectrochemical (PEC) water splitting is a promising way to convert solar energy into hydrogen energy. This study investigated the effect of concentrated light and reaction temperature on the PEC performance of CoPi/Mo:BiVO4 photoanode, and found that concentrated light can effectively enhance the photocurrent density, with the best performance achieved at high temperature.
Photoelectrochemical (PEC) water splitting is a promising way to convert solar energy into hydrogen energy. It is typically carried out at room temperature (RT) and 1 sun illumination. The PEC water splitting under concentrated light is expected to be an effective route to improve PEC performance, but there are few studies on it. Herein, CoPi/Mo:BiVO4 photoanode was selected to investigate the effect of concentrated light and the reaction temperature on its PEC performance. It was revealed that CoPi/Mo:BiVO4 showed enhanced PEC performance under concentrated light. The photocurrent density was enhanced with increased light intensity and increased reaction temperature. At a high temperature (60 degrees C), the normalized photocurrent density (3.31 mA cm-2 at 1.23 V vs. RHE) was found to be optimal at 4 suns, which was attributed to the synergistic effect of concentrating light and heating. It is proved that concentrated light can effectively improve the PEC performance, which has important guiding significance to realize the low-cost and efficient PEC water splitting.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据