期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 48, 期 35, 页码 13068-13080出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.12.062
关键词
b-SiC foam; S-I cycle; Pressure drop; Catalytic performance; Hydrogen production
Developing an active, stable, and cost-effective catalytic system for gas-phase SO3 reduction in the Sulfur-Iodine cycle is crucial for large-scale implementation. A copper ferrite catalyst supported on b-SiC foam was synthesized and characterized using various techniques. The conversion of SO3 was evaluated at temperatures of 800-900°C and a WHSV (weight hourly space velocity) of 8.1 h-1. Stability tests were conducted for 300 hours at 850°C and 8.1 h-1 WHSV. The catalytic performance of the b-SiC foam supported copper ferrite catalyst was found to be excellent in this highly endothermic and corrosive reaction.
To develop a highly active, stable, and economical catalytic system for gas-phase SO3 reduction in the Sulfur-Iodine cycle is essential to implement the process at large scale. b -SiC foam supported copper ferrite was synthesized, and characterized by different cutting edge techniques such as XRD, FT-IR, TGA, BET, XPS, TEM, HR-TEM, FESEM-EDS and elemental mapping. The conversion of SO3 was evaluated in the temperature range of 800 -900 degrees C, and at 8.1 h-1 WHSV. The stability test, 300 h time-on-stream, was conducted at 850 degrees C and 8.1 h-1 WHSV. Furthermore, pressure drop, heat transfer coefficients, and mass transfer coefficients were evaluated in a packed bed reactor and based on the obtained results a comparative study was performed between copper ferrite supported on b-SiC foam and the pelletized catalyst. In this extremely endothermic and corrosive reaction, b -SiC foam supported copper ferrite has displayed remarkable catalytic performance. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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