期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 48, 期 27, 页码 10108-10117出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.12.128
关键词
NiCo-LDH nanofibers; Co(OH)2 nanosheets; Electrode materials; Electrochemical energy storage
In this study, an electrode material composed of NiCo-LDH nanofibers and cobalt hydroxide nanosheets was constructed to enhance capacitance performance. The material exhibited excellent specific capacitance and cycling stability, demonstrating great potential for energy storage applications.
Layered double hydroxides (LDHs) have been considered as excellent pseudocapacitive electrode materials for supercapacitors because of their controllable layered structures and high theoretical specific capacitances. However, poor conductivity and shortage of effective active sites hinder their applications. Herein, in order to boost the capacitance perfor-mance, an electrode material composed of NiCo-LDH nanofibers with cobalt hydroxide (Co(OH)2) nanosheets firmly anchored to or uniformly immobilized onto NiCo-LDH nano -fibers surface is constructed. The material architecture takes advantage of superior capacitive activity from Co(OH)2 with good electronic conductivity and dispersibility over the surface of NiCo-LDH nanofibers. The merits based on the elegant synergy between NiCo-LDH nanofibers and Co(OH)2 nanosheets induce an outstanding specific capacitance of 858.9 F/g at a current density of 0.5 A/g. With the current density increasing from 0.5 to 10 A/g, the specific capacitance retention is 67.3%, indicating a good rate capability. Furthermore, the electrode material exhibits a capacitance retention of 83.7% after 2000 cycles at 10 A/g. These excellent electrochemical properties are due to the hierarchically designed structure and the cooperative contributions of NiCo-LDH nanofibers and Co(OH)2 nanosheets, which shows great potential for energy storage applications.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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