A magnetic MIL-125-NH2@chitosan composite as a separable adsorbent for the removal of Cr(VI) from wastewater

Metal-organic frameworks (MOFs) are gradually used since of their huge specific surface area and superior pore structure. However, there are problems such as easy aggregation and difficult separation in water treatment. In this study, we prepared composite microspheres (FMCS-1) by modifying MIL-125-NH2 with Fe3O4 and chitosan. The structural characterization and performance analysis of the materials showed that the introduction of chi-tosan effectively prevents the stacking of MOFs. The magnetic test manifested that Fe3O4 solved the problem of the difficult separation of MOFs from water. The removal potential of toxic Cr(VI) was tested by adsorption experiments. The isotherm model indicated that FMCS-1 is a single molecular layer adsorbent with a maximum adsorption capacity of 109.46 mg/g at pH = 2. The adsorption kinetics showed that the adsorption of Cr(VI) by FMCS-1 was chemical adsorption. The acid resistance test demonstrated that FMCS-1 can exist stably in acid solutions. The recycling experiments proved that the adsorbent can be reused and the removal percentage still reaches 50 % after 5 cycles. This work expands the application of MOFs in water treatment and also provides an effective adsorbent for Cr(VI) removal.

Automated summary

In this study, composite microspheres FMCS-1 were prepared by modifying MIL-125-NH2 with Fe3O4 and chitosan. The introduction of chitosan effectively prevents the stacking of MOFs, and Fe3O4 solves the problem of difficult separation. FMCS-1 exhibited a maximum adsorption capacity of 109.46 mg/g for toxic Cr(VI) at pH = 2. The adsorption of Cr(VI) by FMCS-1 was chemical adsorption and FMCS-1 showed acid resistance and recyclability. This work expands the application of MOFs in water treatment and provides an effective adsorbent for Cr(VI) removal.