Synthesis of starch-based smart hydrogel derived from rice-cooked wastewater for agricultural use

The synthesis of biodegradable hydrogel based on naturally available macromolecules is an important area of research. We synthesized new hydrogel using rice-cooked wastewater (starch), acrylamide, and 2-acrylamido-2methylpropansulfonic acid in an aqueous medium. The synthesis approach is facile, low-cost, eco-friendly, and novel. The synthesized materials were characterized by scanning electron microscope, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and Thermogravimetric analysis. The hydrogel exhibited maximum tap water absorbency (158.3 g/g) at pH 7, saline water absorbency (50 g/g), urea solution absorbency (141.2 g/g) at 24 h, and excellent water retention capability (47 wt % at 70 degrees C, 12 h, and 89 wt% at 30 degrees C, 24 h). Chili plants, mung beans, and pea seeds germinated and grew well in the hydrogel and hydrogel-mixed soil, respectively. The biodegradability study shows 34.6 % at 120 days in soil and 6.5 % at 30 days in the open air. These findings could entice agricultural development in dry soil.

Automated summary

The synthesis of biodegradable hydrogel using rice-cooked wastewater, acrylamide, and 2-acrylamido-2-methylpropansulfonic acid showed promising characteristics such as high water absorbency, excellent water retention capability, and good biodegradability. The hydrogel also promoted the growth of chili plants, mung beans, and pea seeds. These findings have the potential to improve agricultural development in dry soil conditions.