期刊
INORGANICA CHIMICA ACTA
卷 545, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2022.121280
关键词
Pyrene; Polyoxometalate; Anderson; Organic-inorganic hybrid compounds
In this study, symmetrical chloride-functionalized Anderson type POM was used as a building block for further POM post-functionalization with organic pyrene compounds. Two novel organic-inorganic hybrid pyrene-POM compounds were designed, synthesized, and fully characterized. The photophysical and electrochemical properties of these compounds were investigated. The organic-inorganic hybrids retained the unique photophysical properties of their precursor pyrene compounds while the functionalization of inorganic POM moiety with organic bis-pyrene compound influenced the redox properties of the Mn-Anderson core.
Symmetrical chloride-functionalized Anderson type POM afterwards used as a building block for onward POM post-functionalization with organic pyrene compounds and two novel organic-inorganic hybrid pyrene-POM compounds were designed, synthesized, and fully characterized. Photophysical and electrochemical properties of these compounds were investigated. Organic-inorganic hybrids retained the unique photophysical properties of their precursor pyrene compounds. Additionally, functionalization of inorganic POM moiety with organic bis-pyrene compound influenced the redox properties of the Mn-Anderson core.
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