4.7 Article

New pyrazole compounds as a corrosion inhibitor of stainless steel in 2.0 M H2SO4 medium: Electrochemical and theoretical insights

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INORGANIC CHEMISTRY COMMUNICATIONS
卷 147, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.inoche.2022.110150

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Pyrazole; Inhibition; Steel; Sulfuric acid; Impedance; Protonation; Simulation

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This paper investigates the adsorption of two novel heterocyclic compounds on the stainless steel surface in 2.0 M H2SO4. The inhibitory properties of the compounds increase with concentration. The inhibition efficiencies of Py-1 and Py-2 are 96.7% and 90.9% respectively. The adsorption of the inhibitors follows the Langmuir Isotherm adsorption model.
The present paper examines the adsorption of two novel heterocyclic compounds of the pyrazole derivatives, namely, Ethyl 1-amino-3-(2-chlorophenyl)-5,10-dioxo-5,10-dihydro-1H-pyrazolo[1,2-b] phthalazine-2 carbox-ylate (Py-1) and Ethyl 1-amino-5,10-dioxo-3-(p-tolyl)-5,10-dihydro-1H-pyrazolo[1,2-b] phthalazine-2-carboxylate (Py-2) against the oxidation of stainless steel in 2.0 M H2SO4. The EIS and PDP demonstrate that the inhibitory properties of both compounds under investigation grow with concentration. Inhibition efficiencies of Py-1 and Py-2 followed the order: 90.9% (Py-2) < 96.7% (Py-1). the intensity-potential curves show that Py-1 & Py-2 imparted high resistance and acted as anodic type inhibitors. According to the Langmuir Isotherm adsorption model, the tested inhibitors have been deposited on the stainless-steel surface. The impedance dia-grams also include two semicircles, the first of which was linked to the development of protective inhibitor films and the second to the process of charge transfer. SEM/EDX analyses were performed to describe the chemical makeup of the layer that had formed on the steel's surface. Theoretical studies, such as MD simulation and DFT, have helped to better elucidate the understanding of the process of corrosion inhibition.

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