4.7 Article

External-Field-Independent Thermometric Sensitivity and Green Emission of Upconversion Phosphor Sr2InF7: Yb3+, Er3+

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INORGANIC CHEMISTRY
卷 -, 期 -, 页码 -

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AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c03379

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资金

  1. National Natural Science Foundation of China
  2. Youth Innovation Team of Shaanxi Universities
  3. Foundation of Shaanxi Educational Committee
  4. Thousand Talents Plan of Jiangxi Province
  5. [11974278]
  6. [51672215]
  7. [15JK1709]
  8. [jxsq2020102064]

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In this study, a noncontact upconversion optical temperature sensor was developed and a flexible thin-film thermometer was fabricated for detecting the temperature of microelectronic components. The results showed stable emission and sensitivity of the sensor, indicating its potential to replace traditional thermometers.
Based on luminescence intensity ratio (LIR) technology, the noncontact upconversion (UC) optical temperature sensor has aroused a great deal of interest due to its great application prospects in some extreme environments. However, most of the studies focused on improving its sensitivity due to the fact that the sensitivity can be influenced by many external field factors, such as the power density and pulse width of pumping sources or temperature. Herein, a green-emitting UC phosphor Sr2InF7: Yb3+, Er3+ was developed as a potential thermometer, which retained bright green emission under 980 nm excitation with different pulse widths and power densities or at different temperatures; the possible mechanisms are discussed in detail. Its sensitivity almost remained constant when using both continuous wave (c.w.) and pulsed laser or different power densities, which meant the sensitivity of Sr2InF7: Yb3+, Er3+ was independent of the characteristics of pumping laser. A flexible thin-film thermometer composed of Sr2InF7: 2%Yb3+, 2%Er3+ was also fabricated to detect the temperature of microelectronic components, which can not only accurately measure the temperature of the working electronic circuit board but also exhibit excellent repeatability. The results indicated that the present noncontact UC temperature sensor showed stable green emission and thermometric sensitivity as well as the possibility of replacing the traditional thermometers.

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