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Metalation of Tellurophene: Reactivity of 21,23-Ditelluraporphodimethene toward Palladium(II), Platinum(II), and Rhodium(I)

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INORGANIC CHEMISTRY
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AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c03777

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Ditelluraporphodimethene, a nonaromatic porphyrinoid, undergoes different reactions with palladium(II), platinum(II), and rhodium(I). Palladium(II) forms a side-on coordination compound with two tellurium donors, while platinum(II) or rhodium(I) leads to the formation of organometallic species with metallacyclopentadiene rings. The substitution reaction selectively occurs at the conjugated part of the molecule, resulting in the incorporation of a metallacyclopentadiene ring into a porphodimethene skeleton.
Ditelluraporphodimethene, a nonaromatic porphyrinoid containing two tellurophene rings, reacted with palladium(II), platinum(II), and rhodium(I) following two different paths. Palladium(II) formed bonds to two tellurium donors of the macrocycle, yielding a side-on coordination compound, with a square planar (Te2Cl2) metal ion environment. An alternative reaction path has been observed for ditelluraporphodimethene with platinum(II) or rhodium(I) in high boiling solvents. These conditions led to the profound transformation, that is, one tellurium atom to a metal atom exchange, resulting in the formation of organometallic species containing metallacyclopentadiene rings, that is, 21-platina-23-telluraporphodimethene and 21-rhoda23-telluraporphodimethene. The substitution reaction proceeded selectively at the tellurophene ring within the conjugated part of the molecule, that is, the tellurophene ring bound to two sp2 meso-carbon atoms. In the case of platinum, the exchange was accompanied by one meso-aryl ring fusion with the formed platinacyclopentadiene ring, and the platinum(II) macrocycle underwent reversible oxidation with chlorine. The products are stable and represent first nonaromatic examples of metalloporphyrinoids, with a metallacyclopentadiene ring incorporated into a porphodimethene skeleton.

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