Structure and Luminescence Studies of a Ce3+-Activated Ba5La3MgAl3O15 Green-Emitting Phosphor

Novel green-emitting Ba5La3MgAl3O15:Ce3+ (BLMAO:Ce3+) is successfully obtained by a solid-state reaction. In this study, BLMAO, which is inspired from the Ba6La2A1.5Fe2.5O15 crystal structure, shows a green emission approximately peaked around 500 nm under near-ultraviolet light excitation at 412 nm by Ce3+ doping. Moreover, internal and external quantum efficiencies of BLMAO:0.02Ce3+ are found to be 27 and 22%, respectively. The emission peak deconvolution and Dorenbos model calculation reveal that the Ce3+ ion occupies on two different crystallographic sites. The potential of BLMAO:Ce3+ for phosphor-converted white LEDs (pc-wLEDs) is systematically evaluated from the results of Rietveld refinement and luminescence measurement.

Automated summary

A novel green-emitting Ba5La3MgAl3O15:Ce3+ (BLMAO:Ce3+) phosphor was successfully synthesized by a solid-state reaction. BLMAO, inspired by the crystal structure of Ba6La2A1.5Fe2.5O15, exhibited a green emission with a peak around 500 nm under near-ultraviolet light excitation at 412 nm due to Ce3+ doping. The internal and external quantum efficiencies of BLMAO:0.02Ce3+ were found to be 27% and 22%, respectively. The position of Ce3+ ion in the crystal lattice was determined through emission peak deconvolution and Dorenbos model calculation. The potential of BLMAO:Ce3+ for phosphor-converted white LEDs (pc-wLEDs) was systematically evaluated based on Rietveld refinement and luminescence measurement.