期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 810, 期 -, 页码 25-32出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2016.03.005
关键词
Phthalocyanine; Phthalonitrile; Iron; Cobalt; Phenolic compounds; Oxidation
资金
- Research Fund of Karadeniz Technical University (Trabzon-Turkey) [5302]
4-[2-(2,3-dichlorophenoxy)ethoxy] substituted Co(II) and Fe(II) phthalocyanines were successfully synthesized and characterized by the spectroscopic methods (IR, H-1 NMR, UV-Vis, mass spectrometry and elemental analysis). Determination of the optimal conditions for oxidation of phenolic compounds, the catalytic reactions were carried out change the reaction temperature, time and different oxidants, subst./cat. ratio. In the presence of phthalocyanine derivatives 4 and 5, we demonstrated that phenolic compounds oxidize to the less harmfull products with high conversion and yield. Additionally, the computational studies of 4-[2-(2,3-dichlorophenoxy) ethoxy]phthalonitrile were done in this work. (C) 2016 Elsevier B.V. All rights reserved.
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