期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 10, 页码 4002-4011出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00129
关键词
-
资金
- National Natural Science Foundation of China [21272217, 21502173]
A nickel(II)-catalyzed alkynylation/annulation cascade via double C-H cleavage has been successfully achieved. This methodology adopted a removable N,O-bidentate directing group with a broad range of amide substrates and terminal alkynes being well tolerated. The catalytic system allowed for atom-economical and environmentally benign one-pot construction of the corresponding 3-methyleneisoindolin-1-one derivatives using O-2 as the external oxidant.
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