期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 16, 页码 7139-7147出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01001
关键词
-
资金
- DFG (Graduiertenkolleg Photocatalysis) [1626]
- Studienstiftung des Deutschen Volkes and Fonds der Chemischen Industrie
A photo-redox-catalyzed procedure for the one-step formation of sultones from alpha,omega-alkenols and trifluoromethylsulfonyl chloride is described. Using [Cu(dap)(2)]Cl (1 mol %), a wide range of substrates can be cleanly converted to the target compounds, while commonly employed photoelectron transfer catalysts such as [Ru(bpy)(3)]Cl-2 or fac-Ir(ppy)(3) fail in this transformation. The obtained fluorinated sultones are attractive as potential electrolyte additives or as structural motifs in drug synthesis, with the latter being demonstrated with the synthesis of a trifluoroethyl-substituted analogue of a benzoxathiin that has high anti-arrhythmic activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据