期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 14, 页码 6100-6105出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00985
关键词
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资金
- German Research Council (DFG) by an Emmy-Noether grant [CZ 183/1]
The total synthesis of enantiomerically pure (+)-mesembrine is described. The central pyrrolidine moiety incorporating a quaternary, all-carbon-substituted stereocenter was constructed employing an asymmetric gold-catalyzed cydoisomerization of a 1,4-diynamide.
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