期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 22, 页码 11162-11167出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02145
关键词
-
资金
- National Natural Science Foundation of China [21362022, 21302084]
A copper-mediated oxidative functionalization of C(sp(3))-H bonds with isoquinolines via a radical process without ligands was achieved. The present system exhibits a novel pathway for the preparation of N-alkyl (benzyl) isoquinolin-1(2H)-ones in moderate to high yields. In addition, this procedure provides a simple method to afford 5-oxaprotoberberinones and their derivatives in two steps.
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