期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 10, 页码 4378-4385出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00472
关键词
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资金
- DST [SB/S1/OC-19/2013]
- CSIR
- Government of India
An interesting domino reaction of 5-membered cyclic sulfamidate imines with a variety of Morita-Baylis-Hillman acetates of nitroolefins/nitrodienes in the presence of DABCO as an organic base at 55 degrees C is reported for the first time. This new synthetic strategy provides a series of pharmacologically interesting 4,6-diarylpicolinates in high to excellent yields and allows several compatible functionalities on aryl rings. Moreover, the biologically interesting imidazo[1,2-a]pyridine (alpidem derivative) has been prepared in high chemical yield through a unique procedure.
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