期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 16, 页码 7244-7249出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01240
关键词
-
资金
- Merck Research Laboratories
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001011]
The emergence of visible light photoredox catalysis has enabled the productive use of lower energy radiation, leading to highly selective reaction platforms. Polypyridyl complexes of iridium and ruthenium have served as popular photocatalysts in recent years due to their long excited state lifetimes and useful redox windows, leading to the development of diverse photoredox-catalyzed transformations. The low abundances of Ir and Ru in the earth's crust and, hence, cost make these catalysts nonsustainable and have limited their application in industrial-scale manufacturing. Herein, we report a series of novel acridinium salts as alternatives to iridium photoredox catalysts and show their comparability to the ubiquitous [Ir(dF-CF3-ppy)(2)(dtbpy)](PF6).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据