期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 20, 页码 10043-10048出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01932
关键词
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资金
- National Natural Science Foundation of China [21242002]
- Science and Technology Planning Project of Guangdong Province [2015A020211026]
- 100 Young Talents Program of Guangdong University of Technology [220413506]
A novel and efficient electrophilic fluorination of secondary phosphine oxides with Selectfluor has been achieved. This transformation provides direct access to phosphoric fluorides in up to 92% yield under mild conditions. In addition, P-O bond construction via a one-pot coupling process of secondary phosphine oxides with water or alcohols in the presence of Selectfluor leads to the formation of phosphinic acids or phosphinates in up to 96% yield.
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