期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 13, 页码 5655-5662出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00390
关键词
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资金
- National Natural Science Foundation of China [21572083, 21322201, 21290180]
- Fundamental Research Funds for the Central Universities [lzujbky-2015-48]
- State Key Laboratory of Natural and Biomimetic Drugs [K20150213]
- PCSIRT [IRT_15R28]
- 111 Project of Ministry of Education of China [111-2-17]
- Chang Jiang Scholars Program
A novel strategy based on phase transfer catalysis for the diastereoselective and enantioselective direct assembly of unsymmetric beta,beta-diaryl-alpha-amino acid esters via 1,6-conjugate addition of para-quinone methides and glycine derivatives is described. This protocol also provides an alternative route to the synthetically interesting functionalized chiral tetrahydroisoquinoline and its analogues.
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