期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 22, 页码 11305-11311出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02276
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Generation of ortho-SF5-benzyne was achieved by a lithiation/elimination sequence starting from 2-fluoroSF(5)-benzene. The highly reactive ortho-SF5-benzyne intermediate was trapped by furan or 2-methylfiiran in situ, and the obtained stable Diels Alder adducts were subjected to the series of further chemical transformation, which led to the formation of previously unknown 1-SF(5-)naphthalene and its derivatives with bromo, amino, hydroxy, and methyl substituents, including bis-SF5-substituted naphthalenes. NMR spectroscopy experiments revealed characteristic through-space coupling between the SF5-group's equatorial fluorines and proton/carbon nuclei of -H, -CH3, and -OH substituents naphthalenes. in the pen-position to the SF5-group of 1-SF5-naphthalenes
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