期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 5, 页码 2106-2112出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00134
关键词
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资金
- MEXT [15H01086]
- [15K21143]
- Grants-in-Aid for Scientific Research [26288016, 15H01086, 25248007, 24109002] Funding Source: KAKEN
We report variable and unique properties of 1,2-di(9-anthryl)benzene 1 as a fundamental moiety of anthracene-based pi-cluster molecules. Due to a through space pi-conjugation between anthracene units, excimer emission at room temperature and charge delocalized state in radical cation state of 1 could be observed. Photoirradiation to 1 afforded an intramolecular [4 + 4] cyclized anthracene dimer 1' having a high strain energy with long C-C bond that exceeded 1.68 angstrom, resulting in C-C bond dissociation by simple mechanical grinding.
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